-Under "Accessory Settings" on your PS3, locate and select "Manage Bluetooth devices". Select "Register New Device." The PS3 will begin Bluetooth scanning. Simultaneously press and hold the DualShock 4's "Share" and "PS" buttons until the controller light bar starts blinking. The controller should then appear in the PS3's list as a "Wireless Controller."
The DualShock 4 can be used wirelessly on the PC. Go to the "Control Panel" in the "Start" menu. Then type in the search bar: Devices and Printers. Then click "Add new device" and hold down the Share and PS Button on the controller until the Light Bar on the controller starts flashing. The PC will recognize the device as "Wireless Controller" and then you can register it.
Have you considered getting a gamepad for PC? Unfortunately, developers seem to be spending less and less effort on good controls for PC ports of console games. I recently got so fed up with this that I just gave in and bought a USB controller (Assassin's Creed PC controls pushed me over the edge).
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